Oligomerization of C9 hydrocarbon fraction initiated by amino peroxides with cyclic substitute
نویسندگان
چکیده
This paper investigates the production of hydrocarbon resins by oligomerization in solution and suspension C9 fraction by-products from oil refining. The disadvantage existing technologies for oligomers free radical is use high reaction temperatures. application N-replaced amino peroxides as low-temperature initiators a technology can reduce temperature duration reaction. correlation between parameters yield characteristics has been established. Owing to this, it will be possible set optimal conditions predict properties resulting products. values bromine number (–0.98 –0.95) (–0.83 –0.80) indicate course main factor influencing (correlation 0.80). softening range 349‒353 K does not depend on indicator 0.18). Suspension studied intervals −0.08) initiator concentration 0.40). It proved that variables, depends 0.88). color products at varies slightly 20–30 mg I2/100 ml. established make effectively refining synthesizing light oligomers. Under conditions, product 22.7 % with 19.4 oligomerization.
منابع مشابه
Synthesis of unstable cyclic peroxides for chemiluminescence studies
Peróxidos cíclicos de quatro membros são intermediários de alta energia importantes em diversas transformações quimi e bioluminescentes. Especificamente, a-peroxilactonas (1,2-dioxetanonas) têm sido consideradas sistemas modelo para a eficiente bioluminescência do vaga-lume. Contudo, a preparação deste tipo de compostos altamente instáveis é extremamente difícil e, por isso, apenas alguns pouco...
متن کاملSelective synthesis of cyclic peroxides from triketones and H2O2.
A method for the assembly of tricyclic structures containing the peroxide, monoperoxyacetal, and acetal moieties was developed based on the acid-catalyzed reaction of β,δ-triketones with H(2)O(2). Tricyclic compounds are formed selectively in yields from 39% to 90% by the reactions with the use of large amounts of strong acids, such as H(2)SO(4), HClO(4), or HBF(4), which act both as the cataly...
متن کاملThe action of iron on amino acid and protein peroxides.
Protein oxidation by agents such as oxygen free radicals leads to changes in their stucture and function. Depending on the conditions of the oxidation, proteins can undergo chain scission and crosslinking, loss of amino acids, increase in susceptibility to proteolysis and heat denaturation and loss of biological activity [l-71. We have recently reported that, in addition to such alterations, so...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Eastern-European Journal of Enterprise Technologies
سال: 2022
ISSN: ['1729-3774', '1729-4061']
DOI: https://doi.org/10.15587/1729-4061.2022.259892